Description:
A NaS battery consists of liquid (molten) sulfur at the positive electrode and liquid (molten) sodium at the negative electrode as active materials separated by a solid beta alumina ceramic electrolyte. The electrolyte allows only the positive sodium ions to go through it and combine with the sulfur to form sodium polysulfides.
2Na + 4S = Na2S4
During discharge, as positive Na+ ions flow through the electrolyte and electrons flow in the external circuit of the battery producing about 2 volts. This process is reversible as charging causes sodium polysulfides to release the positive sodium ions back through the electrolyte to recombine as elemental sodium. The battery is kept at about 300 degrees C to allow this process.
NaS battery cells are efficient ( about 89%) and have a pulse power capability over six times their continuous rating (for 30 seconds). This attribute enables the NaS battery to be economically used in combined power quality and peak shaving applications.
Deployment Status:
NaS battery technology has been demonstrated at over 30 sites in Japan totaling more than 20 MW with stored energy suitable for 8 hours daily peak shaving. The largest NaS installation is a 6MW, 8h unit for Tokyo Electric Power company. Combined power quality and peak shaving applications in the U.S. market are under evaluation. Commercial production of the basic building block - the NAS 50kW, 360 kWh module - is targeted for early 2003.
Developers / Suppliers:
NGK